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Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides

Kerry Ann Ness and Marie E Migaud

School of Chemistry and Chemical Engineering, Stranmillis Road, Queens University, Belfast, BT9 5AG, Northern Ireland, UK

Beilstein Journal of Organic Chemistry 2007, 3:26doi:10.1186/1860-5397-3-26

Published: 26 September 2007

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Abstract

We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene α-D-glucopyranoside in high yields and which does not require the use of catalysts.

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